I know to keep the distro small [I love The One CD Deal] you have to leave certain things out. I would love a Fireworks, like program. A good drawing app. Maybe a PS clone that supports CMYK out the box :). I was thinking that you might have a supplemental CD that a user could DL that has a BLAG GFX SUITE.
I was thinking something like BLArtist (A Vector drawing app with more capabilities than Sodipodi), then BLAGoto (a raster photo program, but with DTP in mind, based off CMYK, and pantone), BLAGWorks (a we gfx program that uses the PNG format, and has the capabilities of Macromedia Fireworks), last but not least BLAver (a web WYSIWYG editor like DreamWeaver).